The degree of curing describes the conversion rate achieved during crosslinking reactions (curing). In macromolecular chemistry, crosslinking refers to reactions in which a large number of individual molecules are linked to form a three-dimensional network. Linkage can be achieved either by direct setup of macromolecules or reaction to the already existing polymers.
This can easily be measured by means of differential scanning calorimetry (DSC).
The degree of curing, α, is the amount of heat converted divided by the reaction enthalpy.
α = H/ΔHR
The degree of cure of an already (partially) crosslinked sample can be determined via the residual enthalpy of post-crosslinking, HPC (post-cure). Then, the degree of cure can be calculated as
α = 1-(HPC/ΔHR)
Figure 1 depicts an example for the calculation of the degree of cure for a partially cured adhesive. The uncured adhesive shows a curing enthalpy of 242.35 J/g, whereas the partially cured sample shows an enthalpy of just 203.92 J/g for the post curing reaction. Therefore, a degree of cure of 15.9 % for the partially cured sample can be calculated.